CONSTANTES DE COUPLAGE 13C-13C. CONFORMATION DES ACIDES ...

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Dans ces conditions, les constantes de couplage l3C-13C ont pu être mesurées à différents pH. Elles rendent compte d'une part, des degrés d'ionisation et de protonation des groupements C-terminaux, et d'autre part mettent en évidence I'influence spatiale des groupements Net C-terminaux sur les chaînes latérales apolaires. L'introduction d'un acide aminé enrichi dans les peptides peut ...


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